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Что (кто) такое calomel$10790$ - определение

REFERENCE ELECTRODE

Calomel electrode; Calomel half-cellar; Calomel reference electrode

Saturated calomel electrode

The saturated calomel electrode (SCE) is a reference electrode based on the reaction between elemental mercury and mercury(I) chloride. It has been widely replaced by the silver chloride electrode, however the calomel electrode has a reputation of being more robust.

https://en.wikipedia.org/wiki/Saturated_calomel_electrode

Calomel

MINERAL FORM OF THE MERCURY(I) CHLORIDE

Sweet mercury

·noun Mild chloride of mercury, Hg₂Cl₂, a heavy, white or yellowish white substance, insoluble and tasteless, much used in medicine as a mercurial and purgative; mercurous chloride. It occurs native as the mineral horn quicksilver.

calomel

MINERAL FORM OF THE MERCURY(I) CHLORIDE

Sweet mercury

n.

Chloride of mercury, protochloride of mercury, subchloride of mercury, mercurous chloride.

Википедия

Saturated calomel electrode

The saturated calomel electrode (SCE) is a reference electrode based on the reaction between elemental mercury and mercury(I) chloride. It has been widely replaced by the silver chloride electrode, however the calomel electrode has a reputation of being more robust. The aqueous phase in contact with the mercury and the mercury(I) chloride (Hg₂Cl₂, "calomel") is a saturated solution of potassium chloride in water. The electrode is normally linked via a porous frit to the solution in which the other electrode is immersed. This porous frit is a salt bridge.

In cell notation the electrode is written as:

{\ce {{Cl^{-}}(4M)|{Hg2Cl2(s)}|{Hg(l)}|Pt}}

https://en.wikipedia.org/wiki/Saturated calomel electrode